Why do Refractory Plastics Need to be Trapped?

KilnRefractory

RS refractory plastic manufacturer, how many types of refractory plastic are there? Refractory plastic is divided into different materials such as clay, high alumina, aluminum carbide silicon, silicon, magnesium, etc., and the binder includes different types of binders such as water glass and phosphoric acid. In the types actually used, phosphoric acid binder is relatively more used. However, the refractory plastic combined with phosphoric acid binder must be trapped, and the trapping time must not be less than 18-24 hours.

RS High Quality Plastic Refractory
RS High Quality Plastic Refractory

Reasons for Trapping Refractory Plastics

The reason why refractory plastics need to be trapped is that there are certain impurities in the raw materials of plastics, which react with phosphate binders. After the reaction, a large amount of gas will be formed, which will cause the internal expansion of the plastic, resulting in a loose structure of the material and a decrease in strength after hardening. The purpose of trapping is to allow the gas to be fully discharged after a period of time. After the gas is discharged or during construction, the remaining binder is added, so that the use function of the plastic can be fully utilized.

If it is a plastic combined with water glass, the binder can be added during on-site construction. At present, due to technological innovation, refractory plastics are squeezed into small cubes by an extruder before use, packaged in plastic bags for storage, and can be opened for use when used, so there is no problem of trapped materials. Because the materials have been trapped during the storage process. This type of production extrusion is generally only used for export products.

Refractory plastics are not extruded for domestic use. A part of the binder is added during the production process, and the material is trapped during the transportation process. When using, open it and add the remaining binder to mix it, and it can be used directly. But it should be noted that the time must be controlled within 18-24 hours. If it is a short-distance transportation, just control the time and use it. Trapping the material on site delays labor. If the material is trapped first, there is no need to trap the material on site, which saves time and meets the construction needs.

Corundum Plastic Refractory
Corundum Plastic Refractory

How Can Refractory Plastic be Constructed to Achieve Zero Expansion?

Refractory plastic is easy and quick to construct, and the use state is stable. If you want to achieve zero expansion of plastic, you need to adopt a zero expansion design to offset the expansion and contraction of plastic at high temperature.

Plastic has a certain plasticity at high temperature. Zero expansion of plastic means that it can withstand drastic changes in furnace temperature and resist frequent shutdowns and temperature increases. The mold can be removed immediately after the plastic is constructed. If it is for maintenance, it does not need to be baked and can be put into use directly as the furnace temperature rises.

However, during construction, attention should be paid to the mold drawing construction to ensure that the deformation of the steel structure and the lining furnace is synchronized. In addition, the anchor bricks must be evenly stressed to avoid breakage and collapse during use.

Zero expansion design of refractory plastic

Zero expansion design means that during construction, the mold is first set up to ensure that the construction site is clean, and then the refractory plastic blank is laid on the ramming site. Only a single layer of material can be laid each time, and the hammer head is downward, and the plastic is moved back and forth to make it flat and dense. If the construction reaches the anchor brick, the ramming surface of the refractory plastic should be 16 to 20 mm higher than the bottom surface of the anchor brick. Put the wooden mold on the anchor brick, straighten it and hammer it to make a tooth mark, and the plastic around the anchor brick should be rammed densely.

The construction of refractory plastic should be laid and rammed layer by layer, and each layer should be scraped to keep the same height as the construction surface. If there is a break in the ramming of plastic, the rammed surface should be covered with plastic cloth. If it snows, the surface of the material should be shaved. When the construction is interrupted for a long time, the joint should be left between the two rows of anchor bricks.

Corundum Plastic Refractory
Corundum Plastic Refractory

Description of the Plastic Refractory Used on Furnace Roof

If plastic refractory is used on furnace roof, the force direction of hammer head should be horizontal when ramming, and the material surface joint and furnace roof working surface should be vertical. The peeling layer and material surface joint should not overlap during production. Plastic should be rammed from the material joint on furnace roof. During construction intervals, cut the material vertically into right angles to the furnace shell and cover it with plastic cloth to prevent water loss. Before anchoring bricks or hanging bricks, wooden mold bricks with the same tooth shape should be used to tighten and drive into plastic. After the tooth mark is formed, the anchor brick is embedded and tightened.

After plastic construction, the mold should be removed as soon as possible to dissipate the moisture. When trimming, the plastic around the end of the anchor brick is gently tapped with a wooden hammer or a ramming hammer to make it fit tightly. Trimming includes scraping, piercing air holes or cutting expansion joints.

During construction, refractory plastic cannot come into contact with water; when constructing castables in contact with plastic, waterproofing of plastic is also required; the formwork should be removed as soon as possible before baking to allow the masonry to dry naturally.

Due to the “zero expansion” design of refractory plastic, cracks and expansion areas of the masonry after drying and baking are filled with refractory fibers. To prevent the furnace lining from catching fire and smoking at low temperatures, the cracks and expansion joints will close at around 1350℃.

What is the Effect of the Size of Refractory Plastic Particles when Used?

The particle size of refractory plastic has an effect on construction, but has no effect on use. On the contrary, plastic with large particles will have a longer service life. However, it should be noted that there are still requirements for particles in special parts, especially those that are difficult to construct. The main reason is that if the particles are large, it is not easy to ram and construct, and the construction efficiency is low when the particles are too large. However, if the particles do not exceed 10mm, as long as the construction can go smoothly, there will be no problem in use. And the service life is longer than that of plastics below 3mm.

Plasticity index of refractory plastic. The plasticity index of refractory plastic is 15-40%. If the plasticity index is lower than 15%, the plastic will be too hard and cannot be constructed. However, if the plasticity exceeds 40%, the material will be too soft. Neither too hard nor too soft are not easy to construct, and they are not dense when rammed. The most suitable state of the refractory plastic index is that it can be kneaded into a ball by hand, without water seepage or stickiness.

Refractory plastic has its own characteristics. Generally, the strength at room temperature is low, the strength at medium temperature does not decrease, the strength at high temperature is high, and the thermal shock and peeling resistance are good. However, the rammed lining during construction must be welded with anchors or supports to improve the performance of refractory plastic and extend its service life.

In short, whether the refractory plastic is trapped on site during construction or the manufacturer adds binders to trap the material, the particle size does not affect the use. On the contrary, the production process ratio of larger particles will have a longer service life than the refractory plastic with smaller particles.

Six Outstanding Advantages of Rongsheng Fiber Reinforced Calcium Silicate Board

KilnRefractory

Rongsheng non-asbestos fiber-reinforced calcium silicate board: based on siliceous and calcium materials (tobermorite generated under high temperature and high pressure), fiber-reinforced, must be autoclaved and cured. Fiber-reinforced calcium silicate board is a high-performance, green, and environmentally friendly building material. Its composition, performance and application are as follows:

Composition of Fiber-Reinforced Calcium Silicate Board

  1. Main materials: Siliceous materials (such as quartz powder, fly ash, diatomaceous earth, rich in SiO₂) and calcium materials (such as lime, calcium carbide mud, cement, rich in CaO) are the main cementing materials.
  2. Reinforcement materials: Loose short fibers such as inorganic mineral fibers or cellulose fibers are used as reinforcement materials.
  3. Manufacturing process: Calcium silicate board with mullite (C₅S₆H₅) crystal structure is generated through pulping, molding, high temperature and high pressure steaming and other processes.
Rongsheng Fiber Reinforced Calcium Silicate Board
Rongsheng Fiber Reinforced Calcium Silicate Board

Performance of Fiber-Reinforced Calcium Silicate Board

  1. Fireproof performance‌: non-combustible A-grade material, does not burn in case of open flame, does not produce toxic smoke, and has a fire resistance limit of more than 90 minutes‌.
  2. ‌Waterproof and moisture-proof‌: stable performance in high humidity environments, not easy to expand or deform, suitable for bathrooms, toilets and other places‌.
  3. ‌Strength and durability‌: high strength, 6mm thick board strength exceeds 9.5mm thick gypsum board, and is not easy to crack or deform‌.
  4. ‌Sound insulation and heat insulation‌: has good sound insulation and heat insulation performance, and the 10mm thick partition wall is better than an ordinary brick wall‌.
  5. ‌Environmental protection‌: non-toxic and harmless, in line with green building materials standards‌.

Application of Fiber-Reinforced Calcium Silicate Board

  1. Construction field: used for interior wall panels, exterior wall panels, ceiling panels, curtain wall lining panels, and composite wall panels.
  2. Industrial field: used as ship bulkhead panels, warehouse shed panels, tunnel siding panels, fireproof ventilation ducts, etc.

Six Outstanding Advantages of Rongsheng Fiber-Reinforced Calcium Silicate Board

  1. Fireproof and flame retardant: It reaches non-combustible A1 fireproof, flame retardant and heat-insulating, and does not produce any harmful gases.
  2. Waterproof and corrosion-resistant: Calcium silicate board has super high waterproof and moisture-proof performance, and is also suitable for high temperature and high humidity spaces.
  3. Super high strength: The strength of 6mm thick calcium silicate board is much greater than that of 9.5mm thick gypsum board, with good wear resistance, not easy to be damaged or cracked, and not easy to deform.
  4. Super long life: Inorganic material, stable performance, acid and alkali resistance, corrosion resistance, moisture resistance, moth resistance and termite resistance, and mission life is much longer than gypsum board.
  5. Energy saving and environmental protection: The thermal insulation effect is better than gypsum board, and it can significantly save energy when used in construction. Good sound insulation effect, no dust, asbestos, formaldehyde, etc., to achieve zero environmental pollution.
  6. Strong decorative effect: The material performance is stable, the temperature deformation is small, the decorative surface style is diverse, it can be customized, fashionable and beautiful.

The material properties of Rongsheng’s asbestos-free reinforced calcium silicate board are determined by chemical reactions (silicon calcium generates tobermorite at high temperatures). Its curing process must be autoclaved. Physical properties: lightweight, good insulation, and resistance to high-temperature deformation. Main uses: indoor fireproof partitions, suspended ceilings, etc. Advantages: Class A fireproof, water-resistant, and moisture-proof, environmentally friendly, and safe.

Calcium silicate board is more suitable for indoor fireproof and heat insulation scenarios. The key to choosing the right board is the application environment and performance requirements! Contact Rongsheng for free samples and quotes.

The Difference between Heat Insulation Materials and Thermal Insulation Materials

KilnRefractory

Strictly speaking, the concept of thermal insulation refers to the change of thermal energy of the object of concern (such as equipment, buildings, etc.), while the concept of thermal insulation, heat insulation, or thermal insulation refers to the heat flow or heat transfer of the heat source. Thermal insulation materials refer to materials that can block the transfer of heat flow, also known as thermal insulation materials (but not the same as thermal insulation materials). Thermal insulation materials can be divided into three categories: void heat insulation materials, heat reflective materials, and materials with both void heat insulation and heat reflective properties.

RS Ceramic Fiber Insulation Materials
RS Ceramic Fiber Insulation Materials

Insulation Materials

Insulation materials are materials or material complexes that are not easy to conduct heat and have significant resistance to heat flow. Their characteristics are: light weight, looseness, porosity, heat preservation, cold preservation, heat insulation, sound absorption, and sound elimination. Generally speaking, insulation materials include the first and third categories of materials mentioned above. Insulation materials can be divided into organic insulation materials (or organic thermal insulation materials) and inorganic insulation materials (or inorganic thermal insulation materials).

In industry idioms, insulation materials often refer to insulation materials suitable for temperatures below 600-700℃. In addition, the industry also refers to insulation materials suitable for low-temperature environments as “cold insulation materials”. Insulation materials suitable for high-temperature environments above 600-800℃ are called “refractory insulation materials“. Insulation materials have lower requirements for thermal conductivity values.

Insulation materials are often referred to as “thermal insulation materials” by people. Here, people do not strictly distinguish the subtle differences between different concepts.

The refractory industry and other industries often use the words “insulation” and “thermal insulation” to refer to lightweight and poorly conductive materials. However, the two are not used consistently and deserve to be reconsidered and unified. In the refractory industry, before the mid-1980s, “insulation materials” and “thermal insulation materials” were used interchangeably. Since then, the term “thermal insulation materials” has been gradually unified, so RS Kiln Refractory Factory will focus on the difference between thermal insulation and heat preservation below.

What is the Difference between Thermal Insulation and Heat Insulation?

  1. The concept of thermal insulation board and heat preservation board

Thermal insulation board refers to a board used to isolate heat transfer, generally referring to a board with a thermal conductivity of less than or equal to 0.065W/m•k, such as foam glass, polystyrene board, etc.

Thermal insulation board refers to a reasonable engineering material used to maintain the temperature inside and outside the building. It is usually made of materials with a thermal conductivity of less than or equal to 0.12W/m•k, such as extruded board, mineral wool board, etc.

  1. Differences between insulation board and heat preservation board

(1) Material properties

The thermal conductivity of insulation board is lower than that of heat preservation board, and the density of heat preservation board is higher than that of heat preservation board. Heat preservation board is generally a porous material with good air tightness, which can block water vapor penetration to a certain extent, but its bearing capacity for gravity load and wind pressure load is poor. The material used for heat preservation board is relatively hard, with high strength, and can withstand greater pressure.

(2) Application

Thermal insulation board is mainly used for moisture-proof, mildew-proof, anti-corrosion, fire-proof and sound-proof, and is also suitable for roof and wall insulation of industrial buildings and high-end residential buildings. The role of heat preservation board is more to improve the living environment of residential buildings, and is mainly used in the fields of exterior wall insulation, roof insulation, cold storage insulation, etc.

(3) Construction method

Thermal insulation board is mostly constructed by pasting, such as binding with polyurethane foam adhesive. It is generally more convenient to directly paste it with brick wall to achieve insulation. The insulation board needs to be installed by hanging, which is more troublesome, especially in high-rise buildings where construction safety issues need to be considered.

  1. Applicable situations

If the building needs to be moisture-proof, mildew-proof, anti-corrosion, fire-proof, sound-proof, etc., it is suitable to use insulation boards. Such as industrial buildings and high-end residences such as pharmaceutical factories, chemical plants, and food factories. If you need to improve the residential living environment, insulation boards are the first choice. It can effectively increase the temperature of the room and keep the indoor temperature stable, thereby reducing energy consumption.

Aluminate Cement and Aluminate Refractory Castable

KilnRefractory

Aluminate cement and aluminate refractory castables. aluminate cement (Al2O3 65～70%, CaO 21～24% low iron type). RS Kiln Refractory Manufacturer is a refractory material manufacturer with rich production and sales experience. RS manufacturer is committed to providing high-quality and long-life refractory lining materials for high-temperature industrial furnaces. Contact Rongsheng for a free quote.

Rongsheng Calcium Aluminate Cement - High Alumina Cement
Rongsheng Calcium Aluminate Cement – High Alumina Cement

Aluminate Cement

Aluminate cement is a refractory cement, which has many names: refractory cement, 625 cement, high alumina cement, CA-50 cement, etc. It has a wide range of applications. In many refractory concretes, aluminate cement is an indispensable refractory binder.

Aluminate cement is a special cement with weak alkaline calcium aluminate as the main component. It is a hydraulic cementitious material made of bauxite and limestone as raw materials, calcined and made of clinker with calcium aluminate as the main component and about 50% alumina content.

The use temperature of aluminate cement can reach 1350℃. If it is mixed with high-alumina aggregate and other refractory materials in proportion to form a refractory castable, the refractory temperature can reach 1700℃.

Aluminate cement can be divided into CA-50 and CA-70 (also called calcium aluminate cement, white) according to the aluminum content. It is a hydraulic cementitious material with fast hardening, early strength, corrosion resistance and high temperature resistance. Aluminate cement is yellow-brown or gray and is widely used in metallurgy, machinery, building materials, petrochemicals, electricity, food and other industries.

Introduction to the uses of aluminate cement

  1. Used to prepare refractory castables and kiln linings.
  2. Suitable for projects that resist sulfate erosion.
  3. Suitable for concrete projects that require rapid hardening and emergency repair projects.
  4. Suitable for winter construction and special projects that require early strength.
  5. Used as raw material for making water purifiers (calcium aluminate powder).
  6. Used as the best raw material for making decorative materials (such as artificial marble, colored road tiles, colored corrugated tiles, etc.).
  7. It is an important component for preparing expansive cement, self-stressed cement and other special cements.
Rongsheng High Alumina Castables Refractory
Rongsheng High Alumina Castables Refractory

Aluminate Refractory Castables

Aluminate Refractory Castables are an important amorphous refractory material, widely used in industrial kilns such as metallurgy, building materials, petrochemicals, and electric power. It consists of refractory aggregate, powder and binder (such as aluminate cement), which is mixed by adding water or other liquids and has good construction performance and high temperature performance.

Aluminate Refractory Castables Aluminate cement is the key binder in aluminate refractory castables. The type and amount of aluminate cement have a significant effect on the performance of the castable. For example, an increase in the amount of CA-50 cement will increase the compressive strength at room temperature, but the compressive strength will decrease after burning at 1200℃, the refractoriness and load softening temperature will also decrease, and the linear shrinkage after burning will also increase. When preparing aluminate refractory castables, in addition to the amount of cement, the amount of water is also a key factor. An increase in the amount of water will lead to a decrease in performance, so the amount of water in the mixture should be minimized to ensure construction and workability. The selection of refractory powder and aggregate will also have an important impact on the performance of castables. Refractory powder can improve the refractory performance of castables, while the type, grade, maximum particle size and particle grading of aggregates are the main factors affecting the performance.

The use of aluminate castable admixtures is also an important means to improve the performance of aluminate refractory castables. Water reducers can improve the fluidity of castables and reduce water consumption, and coagulants and retarders can adjust the setting time of castables. Sintering agents and expansion agents can improve the medium-temperature strength of castables and compensate for shrinkage at high temperatures.

Aluminum Electrolytic Cell in Smelting Industry – Refractory Masonry at the Bottom of the Cell

KilnRefractory

Masonry of the bottom of aluminum electrolytic cells in the smelting industry. After the tank shell inspection is passed, the longitudinal and transverse center lines of the tank are measured and mapped. Determine the reference point for the masonry trench bottom according to the flatness of the trench bottom plate. At this point, use a level to lay out the baseline for each layer of brickwork, and find the center line of the cathode steel rod and window installation according to the requirements of the drawing. Make sure the cathode steel rod is located in the center of the slot shell window U. Draw lines for masonry trough. Asbestos boards, insulation boards, and thermal insulation bricks are dry-laid, while refractory bricks are wet-laid.

Laying of insulation products at the bottom of the trough

The laying of insulation products at the bottom of the trough includes the laying of asbestos boards, insulation boards, and insulation bricks, all of which are dry-laid.

When laying boards and bricks, they should be laid from the horizontal center of the trough to both sides, without laying through seams, and lightly tightened with a wooden hammer. The boards and bricks are cut with a saw, and all gaps in each layer are filled with alumina powder. The gaps around the boards, bricks and troughs are filled with dry anti-seepage materials or refractory particles and compacted. When the insulation board is damaged, it must be reprocessed by sawing, and its specifications must be 2/3 of the design. Local processing of insulation boards is also allowed according to the deformation of the bottom of the trough, but the processing thickness shall not exceed 10mm. When laying each layer of bricks, the seams should be staggered and the gap should be less than 1mm.

Refractory brick masonry at the bottom of the trough

After laying a layer of alumina powder or refractory particles on the surface of the insulation bricks according to the design requirements, use a line board to lay the surface bricks layer by layer, make a long hanging line board, and carve vertical brick lines on its upper surface. When laying bricks, use the line board clamps on the brick layer to be laid, and use the line hammer to hang the lines on the line boards on both sides. In this way, the thickness and longitudinal arrangement of the bricks are controlled, ensuring accurate masonry. Hanging wire at the bottom of masonry trench.

The mortar joint fullness of refractory bricks is greater than 90%, the top joints, side joints and horizontal joints are all built according to the design requirements, and the gaps around the masonry are filled and compacted with refractory particles. After the masonry is completed, clean it up, check it according to the pre-drawn reference line, and measure 9 points on the masonry surface. If problems are found, they should be dealt with until the standards are met. The surface flatness requirement is no more than ±2mm.

Construction of dry anti-seepage material at the bottom of the trench

Before laying dry anti-seepage material on the insulation bricks, first make a special steel template of a certain height according to the compression ratio calculated in advance, and use it in conjunction with a scraper. Generally, dry anti-seepage materials are compacted in two layers. After the first layer of material is added to the calculated height and leveled with a scraper, plastic film and 1mm thick cold-rolled steel plate or plywood are placed on the material. To prevent dust during tamping, use a special reciprocating sand and gravel rammer, tamping about 6,500 times per minute, and tamping is carried out according to the designed route and number of times. After the first layer is completed, check whether the compaction height of the anti-seepage material reaches its compression ratio. If it is qualified, lay the second layer. Use the same method to compact the anti-seepage material to the designed elevation. After compaction is completed, 9 points on the surface of the anti-seepage material are measured and checked according to the pre-drawn reference line. If part of it exceeds the standard, it can be repaired to make the levelness reach ±4mm to ensure the installation size of the cathode carbon block.

Rongsheng refractory material manufacturer can provide refractory lining materials for high-temperature industrial furnaces. Moreover, Rongsheng Manufacturer and professional construction team can provide refractory furnace lining construction services. Contact Rongsheng for more information.

Why is the Expansion Coefficient of Silica Bricks So Large?

KilnRefractory

The main component of silica bricks is silica, and polycrystalline transformation will occur during the production process, so the expansion coefficient of silica bricks is large.

The characteristics of silica bricks are high load softening temperature, but low thermal shock stability and lower refractoriness than general high-alumina bricks. Silica bricks have a volume expansion rate of 1.5~2.2% at a use temperature of 1450℃. Even when silica bricks are produced, the molds must be appropriately scaled according to the expansion coefficient. Leave space for expansion to make the size of silica bricks more accurate.

Rongsheng Silica Bricks for Sale
Rongsheng Silica Bricks for Sale

When silica bricks are produced, the transformation between quartz, tridymite, and cristobalite in the raw materials will destroy the original crystal structure and rearrange the structure. Because the activation performance is large during the firing process, the transformation temperature is high but slow, which produces a large volume expansion effect.

The silicon bricks have little solution formed at the firing temperature and are difficult to fire. A series of physical and chemical changes that occur during the firing process of silicon bricks will cause the size of silicon bricks to increase.

The temperature of silicon bricks changes greatly during the firing process: residual water is discharged from the bricks at 150°C, decomposition begins at 450°C, and dehydration is completed at 450~500°C. There will be a 0.82% volume expansion in the range of 550~650°C, and the solid phase reaction begins between 600~700°C, and the strength of the bricks increases. At 1100°C, the transformation rate of quartz increases, but the specific gravity of the bricks begins to decrease. At this time, the volume of the bricks increases due to the transformation of quartz into a low-specific gravity variant. Cracks will occur in silicon bricks in the range of 1100~1200°C.

The volume of silicon bricks changes during the heating process, at different temperature steps. The changes of silica are divided into 600°C, 600~1100°C, 1100~1250°C and above 1250°C. At 500~600℃, expansion occurs. At 700~800℃, there is micro-contraction. At 1000~1100℃, the contraction is greater. At 1200℃, the quartz transformation accelerates and the body begins to expand violently. The expansion range is different according to the expansion coefficient of different raw material types.

The biggest disadvantage of silica bricks is low thermal shock stability and low refractoriness, but high refractoriness under load. It is suitable for use in kiln linings in acidic atmospheres. To purchase high-quality silica bricks and zero-expansion silica bricks, please contact Rongsheng for free samples and quotes.

Effect of Barite Powder on the Strength of High Alumina Cement – High Temperature Cement

KilnRefractory

High alumina cement, also known as aluminate cement, has the advantages of high early strength, high-temperature resistance, and strong resistance to sulfate corrosion. In recent years, due to the rapid growth of the early strength of high alumina cement, early de-moulding, and tight construction schedules, the number of projects using high alumina cement to prepare concrete has continued to increase. However, the later strength of high alumina cement is unstable, and there is great controversy about its application in engineering. Studies have shown that the use of ultrafine powder as a mixture of high alumina cement can improve the later strength of high alumina cement.

Castable Refractory Cement
Rongsheng Castable Refractory Cement

Effect of Barite Powder on the Strength of High Alumina Cement

Baryte powder, commonly known as barite, is a naturally formed white inorganic salt and a neutral filler. Its relative density is 4.16, and it has the characteristics of light resistance and corrosion resistance, low oil absorption value, opaque to ultraviolet rays and X-rays, and radiation protection. Using natural mineral barite as an additive for aluminate cement can reduce the water requirement of the standard consistency of aluminate cement, improve the strength of cement, reduce the later strength regression, and not reduce the refractoriness of cement.

Adding an appropriate amount of barite powder admixture to high alumina cement can not only improve the early strength of high alumina cement but also inhibit the later strength shrinkage of high alumina cement. The appropriate amount of barite powder can promote the hydration of high alumina cement. The main reason why barite powder inhibits the later strength shrinkage of high alumina cement is that it inhibits the crystal transformation of CAH10 and C2AH8 to C3AH6 in the hydration products of high alumina cement. It should be noted that excessive addition of barite powder may cause the strength of high alumina cement to decrease. Therefore, in practical applications, it is necessary to make adjustments according to specific circumstances.

In general, the effect of barite powder on the strength of high-aluminum cement is a complex issue that requires comprehensive consideration of multiple factors. Future research can further explore the optimal addition amount of barite powder and the differences between different types of high-aluminum cement to better play the application value of barite powder in high-aluminum cement.

What is High-Temperature Resistant Cement? Aluminate, High Aluminum, Refractory

Rongsheng refractory cement sales. Rongsheng high-temperature cement, has many aliases, aluminate cement, high aluminum cement, high strength refractory high temperature resistant cement. It is a special cement that maintains good performance in high-temperature environment. It has high compressive strength, heat resistance, chemical corrosion resistance and low thermal expansion coefficient. It is suitable for engineering projects in harsh environments such as slag, high-temperature gas and chemically corrosive substances. Contact Rongsheng for a free quote.

Rongsheng Calcium Aluminate Cement - High Alumina Cement
Rongsheng Calcium Aluminate Cement – High Alumina Cement

High-temperature resistant cement is mainly used in high-temperature industrial fields such as metallurgy, petrochemical, and electric power. As well as the construction and maintenance of high temperature facilities such as furnaces, chimneys, smelting furnaces, and chemical equipment. Rongsheng high-temperature resistant cement, aluminate cement, refractory cement, high aluminum cement.

The main characteristics of high-temperature resistant cement are as follows:

  1. High-temperature resistance. The sintering temperature of high-temperature resistant cement is as high as 1300-1600 degrees Celsius. It can maintain stable performance in a long-term high-temperature environment and is suitable for various high-temperature facilities and equipment.
  2. High compressive strength. High-temperature cement has high compressive strength, can withstand large mechanical loads, and is suitable for high-strength and high-pressure engineering applications.
  3. Good chemical corrosion resistance. High-temperature resistant cement has good corrosion resistance to a variety of acid, alkali, salt and other chemical media, and can maintain a long service life in harsh chemical environments.
  4. Low thermal expansion coefficient. High-temperature-resistant cement has a low thermal expansion coefficient, can adapt to thermal expansion and contraction in high-temperature environments, and reduces the generation of cracks.
  5. Excellent fire resistance. High temperature-resistant cement has good fire resistance, can effectively prevent the spread of fire, and improves the fire safety performance of buildings.

Detailed Explanation of Ingredients and Process of High-Strength Sulphoaluminate Cement

Take the production of 100 kg of high-strength sulphoaluminate cement as an example. Among them, sulphoaluminate cement clinker: 76 kg; silica fume: 9 kg; dihydrate gypsum: 10 kg; lithium carbonate 1 kg, calcium hydroxide 2 kg and aluminum sulfate 1.5 kg; retarder: 0.5 kg. Weigh the raw materials of each component according to the above mass percentage. After mixing evenly, grind them together to a fineness of 360m2/kg specific surface area to make a finished cement product.

Sulphoaluminate cement. The high-strength sulphoaluminate cement produced by this method has a simple production process, is easy to implement and has low cost. It can effectively adjust the setting time of sulphoaluminate cement to meet the construction requirements of actual projects.

Rongsheng High Alumina Cement Manufacturer

Rongsheng Refractory Material Manufacturer is a powerful manufacturer and seller of refractory materials. Rongsheng’s high alumina cement (CA50/CA60/CA70/CA80, etc.). High temperature resistance and excellent performance. Rongsheng’s refractory products have been sold to more than 120 countries around the world, such as South Africa, Chile, Egypt, Colombia, Uzbekistan, Italy, Indonesia, Ukraine, Hungary, Spain, Kenya, Syria, Zambia, Oman, Venezuela, India, Peru, the United States, Ethiopia, etc. Contact Rongsheng for more information on refractory lining materials.

The Importance of Zirconium Silicate 63-65% in High-Performance Ceramics

KilnRefractory

In the realm of advanced manufacturing, high-performance ceramics have become indispensable due to their unique properties, including hardness, thermal stability, and resistance to wear and corrosion. Among the various materials used to produce these ceramics, zirconium silicate, particularly in the 63-65% purity range, stands out as a crucial component. This blog post delves into the importance of zirconium silicate in high-performance ceramics, exploring its properties, applications, and why it is favored by manufacturers.

Zirconium Silicate (ZrSiO₄) 63-65%

Zirconium silicate (ZrSiO₄) is a naturally occurring mineral derived from zircon. It is processed into a fine powder, which is then used in various industrial applications, most notably in ceramics. The 63-65% purity range of zirconium silicate refers to the concentration of zirconium in the material, which is essential for achieving the desired performance characteristics in high-performance ceramics.

Zirconium Silicate (ZrSiO₄) 63-65%
Zirconium Silicate (ZrSiO₄) 63-65%

Key Properties of Zirconium Silicate

Zirconium silicate possesses several properties that make it ideal for use in high-performance ceramics:

  • High Melting Point: With a melting point of approximately 2550°C, zirconium silicate exhibits excellent thermal stability. This property is vital in ceramic manufacturing, where materials are subjected to extreme temperatures during processing and in their final applications.
  • Chemical Inertness: Zirconium silicate is chemically stable and does not react with most substances. This chemical inertness is crucial in preventing degradation or unwanted reactions during the production and use of ceramics, ensuring that the material retains its integrity over time.
  • Hardness: The hardness of zirconium silicate contributes to the strength and durability of ceramic products. It enhances the resistance of ceramics to mechanical wear and tear, making them suitable for demanding applications.
  • Low Thermal Expansion: Zirconium silicate has a low coefficient of thermal expansion, meaning it does not expand or contract significantly with temperature changes. This property helps to prevent cracking and warping in ceramics, particularly during rapid heating or cooling.
  • Opacity: In ceramic glazes, zirconium silicate is often used as an opacifier, giving the ceramics a bright, white appearance. This opacity is important for achieving consistent color and finish in ceramic products.

The Role of Zirconium Silicate in High-Performance Ceramics

Zirconium silicate 63-65% plays a vital role at various stages of ceramic manufacturing, contributing to both the aesthetic and functional properties of the final products.

Structural Ceramics:

High-performance structural ceramics are used in applications where strength, durability, and resistance to extreme conditions are paramount. Zirconium silicate is often incorporated into these ceramics to enhance their mechanical properties. The material’s hardness and low thermal expansion make it ideal for components that must withstand heavy loads, high temperatures, and thermal cycling without losing their structural integrity.

For example, zirconium silicate is used in the production of ceramic engine components, cutting tools, and protective coatings. These applications demand materials that can perform reliably under stress, and zirconium silicate’s properties make it a preferred choice for such uses.

Refractories:

In the production of refractory ceramics, which are used to line furnaces, kilns, and other high-temperature environments, zirconium silicate 63-65% is invaluable. Its high melting point and chemical inertness ensure that refractory ceramics can endure extreme heat and exposure to aggressive chemicals without degrading.

The inclusion of zirconium silicate in refractory ceramics improves their thermal shock resistance, allowing them to withstand rapid temperature changes without cracking. This makes these ceramics ideal for use in industries such as metallurgy, glass manufacturing, and petrochemicals, where reliable performance in harsh conditions is essential.

Ceramic Glazes:

Zirconium silicate is widely used in the production of ceramic glazes. It acts as an opacifier, providing the glaze with a bright white color and enhancing its opacity. This is particularly important in the production of decorative ceramics, such as tiles, dinnerware, and pottery, where consistent color and finish are key to the product’s aesthetic appeal.

Additionally, zirconium silicate improves the hardness and durability of ceramic glazes, making them more resistant to scratching, chipping, and wear. This ensures that the finished ceramics not only look good but also have a long lifespan, even in demanding environments.

Advanced Ceramics:

Zirconium silicate 63-65% is also used in the production of advanced ceramics, which are engineered for specific industrial applications requiring exceptional performance. These advanced ceramics are used in fields such as electronics, aerospace, and biomedical engineering, where materials must meet stringent standards for strength, durability, and resistance to extreme conditions.

In the electronics industry, for instance, zirconium silicate is used in the production of ceramic substrates and insulators that must operate reliably at high temperatures and in the presence of electrical stress. In the biomedical field, zirconium silicate ceramics are used in the production of implants and prosthetics, where biocompatibility and wear resistance are critical.

Rongsheng Zirconium Silicate for Sale
Zirconium Silicate in High-Performance Ceramics

Advantages of Using Zirconium Silicate in High-Performance Ceramics

The use of zirconium silicate 63-65% in high-performance ceramics offers several significant advantages:

  • Enhanced Durability: The hardness and thermal stability of zirconium silicate contribute to the durability of ceramic products, ensuring that they can withstand wear, heat, and chemical exposure without degrading.
  • Improved Aesthetics: Zirconium silicate’s ability to enhance the opacity and whiteness of ceramic glazes leads to visually appealing products with consistent finishes, which is important in both decorative and functional ceramics.
  • Consistency and Quality: The fine particle size and chemical stability of zirconium silicate powder ensure uniform distribution within the ceramic body and glaze, resulting in high-quality, defect-free products that meet industry standards.
  • Versatility: Zirconium silicate can be used across a wide range of ceramic applications, from structural components and refractories to decorative glazes and advanced ceramics. Its versatility makes it a valuable material for manufacturers seeking to produce high-performance products.
  • Cost-Effective: While zirconium silicate is a high-performance material, it is also cost-effective, offering manufacturers a reliable and affordable solution for enhancing the quality and performance of their ceramic products.

Zirconium Silicate 63-65% is an Essential Material

Zirconium silicate 63-65% is an essential material in the production of high-performance ceramics, offering unique properties that enhance the strength, durability, and aesthetic appeal of the final products. Its high melting point, chemical stability, hardness, low thermal expansion, and opacity make it a preferred choice for a wide range of ceramic applications, from structural and refractory ceramics to glazes and advanced industrial components.

As the demand for high-performance ceramics continues to grow, zirconium silicate will remain a cornerstone of ceramic manufacturing, enabling manufacturers to produce reliable, high-quality products that meet the stringent demands of modern industry. Whether in traditional applications or cutting-edge technologies, zirconium silicate 63-65% will continue to play a crucial role in shaping the future of ceramics. Free quote at Sales@kilnrefractory.com.

Advantages and Disadvantages of Hot Blast Furnace Checker Bricks Silica Checker Bricks and High Alumina Checker Bricks

KilnRefractory

The hot blast stove is a typical regenerative heat exchanger. The regenerator is mainly a porous checker brick, which transfers the heat generated by combustion to the blast furnace blast. The heat transfer of the hot blast stove is an unsteady heat transfer process. The heating and cooling of the checker bricks in the regenerator change periodically with the height and time of the hot blast stove.

The shape of the checker brick is a regular hexagonal prism, that is, the upper and lower end faces are regular hexagons. There are a varying number of through holes arranged in regular triangles between the two end faces. The checker bricks are made of different materials according to their different working temperatures. For parts close to the combustion chamber where the temperature is high, materials with good high-temperature performance and strong anti-adhesion ability should be used, mostly silicone or high-aluminum materials. The temperature of the checkered bricks close to the cold air chamber is low, so clay materials with good low-temperature performance and high strength are selected.

Low Creep High Alumina Checker Bricks
Low Creep High Alumina Checker Bricks

Advantages and Disadvantages of Silica Checker Bricks and High Alumina Checker Bricks

Silica refractory materials are acidic refractory materials and have good resistance to oxides such as CaO, FeO, Fe2O3, etc. It has the advantages of high softening temperature under load, stable volume at high temperatures, and high thermal conductivity. However, the thermal stability at low temperatures (below 800°C) is poor. The specific realization is that the load softening temperature can be as high as (1640-1680℃), which is close to the melting point of tridymite (1670℃). It has very good thermal stability above 800℃ and can adapt to large changes in temperature. The silica bricks used in hot blast stoves have tridymite as the main crystal phase and have stable volume and low creep rate under high-temperature loads. Its anti-adhesion performance is also better than other refractory materials. Proper use can make the hot blast stove structure more stable. However, at 200-300°C and 573°C, the volume suddenly expands due to crystalline transformation, which can easily cause structural damage. Therefore, drastic temperature changes below 600°C should be avoided.

Compared with silica bricks, high-alumina refractory materials have a lower softening temperature under load and poor high-temperature volume stability. However, high-aluminum refractory materials have the advantages of large capacity and good thermal shock stability.

Silica refractory materials have less adsorption of dust in coal gas and have good resistance to oxides such as CaO, FeO, Fe2O3. High-aluminum refractory materials have strong adsorption to dust in coal gas, and the main component is Al2O3, which easily forms a low eutectic with CaO and total iron in the dust. It adsorbs to the body of the checker bricks and then penetrates and erodes.

In terms of damage mechanism, high-aluminum refractory materials have poor adaptability to dust in gas.

Compared with silica bricks, low-creep high-alumina bricks have the disadvantages of poor performance and high price. It is a reasonable choice to use silica bricks in the high-temperature zone of hot blast stoves with high blast temperatures. Silica bricks are almost all used in the high-temperature zones of foreign hot blast stoves.

Silica Checker Brick
Silica Checker Brick

Comparison of Heat Storage between High Alumina Checker Bricks and Silicon Checker Bricks

High alumina check bricks and silicon check bricks are common heat storage materials, and they have their own advantages and characteristics in different application scenarios.

High-aluminum checker bricks are usually made of high-aluminum materials. Their main features are high heat capacity and excellent high-temperature resistance. High-aluminum checker bricks are widely used in high-temperature equipment such as industrial furnaces and kilns, and can effectively store heat and maintain temperature stability. Therefore, it is more suitable for high-temperature operations of 1400-1500℃.

Silicon lattice bricks are usually made of siliceous materials, which are characterized by good thermal conductivity, low density, and strong corrosion resistance. This brick material performs relatively well at 1600°C. For example, long-term operation of industrial furnaces or long-term stable high-temperature environments.

When comparing these two materials, specific application needs and work environments need to be considered. If it is necessary to maintain high temperatures for a long time, silica checker bricks may be more suitable. If frequent temperature changes are required or rapid heating and cooling are required, high-aluminum checker bricks may be more suitable.

Checker Bricks for Hot Blast Stoves Regenerators
Checker Bricks for Hot Blast Stoves Regenerators

How to Increase the Heat Balance and Shorten the Heating Time of Hot Air Furnace Checker Bricks?

Due to the development of modern ironmaking technology, the requirements for blast furnaces are getting higher and higher, and the air temperature requirements are around 1200°C. Obviously, in order to meet the requirements of the blast furnace, in addition to high-intensity combustion to achieve high combustion temperatures, it can only be achieved through efficient and reasonable heat transfer between the airflow and the regenerator structure. Whether the flue gas flow velocity field after combustion can enter the regenerator in a uniformly distributed manner, and whether the uneven airflow distribution can be adjusted to a more uniform distribution after entering the regenerator, is whether the utilization rate of the regenerator can be improved. The key factor to enhance the heat transfer effect.

High-temperature far-infrared radiation coatings have an emissivity above 0.9 in the spectral range of 0.7-15μ. Painting on the surface of hot air stove check bricks can increase the heat and speed of heat absorption and heat storage (heat release) of the check bricks without increasing the weight and weight of the check bricks.

  1. During the combustion period, the high absorption characteristics of the infrared radiation coating are used to enhance the heat absorption speed and heat absorption on the surface of the regenerator. Improve heat storage capacity.
  2. During the air supply period, the high radiation characteristics of the coating are used to increase the air supply temperature and heat release capacity.

In addition, R&D personnel stabilized the blackening agent to improve the anti-aging performance, and make the coating dense, high in strength, and high in temperature resistance, thereby reducing the high-temperature impact of the checker bricks. Increase its corrosion resistance and extend the service life of checkered bricks by more than 25%.

Construction Technology of Alumina-Magnesia Carbon Bricks in Ladle Lining

KilnRefractory

Application of alumina-magnesia carbon bricks in ladles. In order to improve the service life of continuous casting ladles and meet the needs of the development of efficient continuous casting technology, alumina-magnesia carbon bricks for ladles were developed. It can be used in various types of continuous casting ladles to greatly increase the service life of the ladles. Aluminum-magnesium carbon ladle bricks are used in a 300t continuous casting ladle in a steel plant. The ladle age has increased from more than 20 times when first-class high alumina bricks were used to more than 80 times, and the highest is 126 times. There is also a 200t fully continuous casting ladle in a steelmaking plant with out-of-furnace refining, which uses alumina-magnesia carbon bricks and has an average lifespan of 64 times and a maximum of 73 times. The promotion of high-quality aluminum-magnesia-carbon refractory bricks for ladles and the use of aluminum-magnesia-carbon ladle lining bricks have significantly increased the life of the ladle. For example, after using alumina-magnesia carbon lining bricks for a 160t ladle, the average service life is increased to 90 times, and the maximum is 115 times.

Alumina Magnesia Carbon Bricks for Ladle Lining
Alumina Magnesia Carbon Bricks for Ladle Lining

Alumina-magnesia carbon bricks are unfired products made of special-grade high-alumina bauxite clinker, fused magnesia or sintered magnesia and graphite as raw materials, and liquid phenolic resin as a binder. This product has good slag erosion resistance, strong corrosion resistance, good thermal shock resistance, and low price, and is mainly used in the non-slag line parts of the ladle.

Construction Technology and Requirements of Alumina-Magnesia Carbon Bricks as Ladle Lining

Construction sequence of alumina-magnesia carbon bricks as ladle lining. Pouring of the permanent layer of the cladding → Pouring of the permanent layer of the bottom of the cladding → Placement of nozzle seat bricks → Construction of breathable bricks and bottom alumina-magnesia carbon bricks → Filling the gaps with corundum cement → Construction of wall-clad alumina-magnesia carbon refractory bricks and slag-clad magnesia carbon bricks Brick masonry → Aluminum-magnesium castable masonry → Curing → Baking.

Wall-clad alumina-magnesia carbon brick masonry construction

  • 1) Use aluminum-magnesium fire mud for wet masonry, and the masonry mud should not be too thin. The mud between the brick joints needs to be full, and the brick joints should be less than 1mm.
  • 2) Each layer of bricks is laid flat, and the brick joints between layers must be staggered. During masonry construction, the principles of “solid backing, tight seams, and arc closing” should be followed, and the joints between the upper and lower layers must be staggered.
  • 3) The size of the cutting door closing brick should be no less than 50mm, and the door closing part should avoid the trunnion position. The door closing positions between layers should be staggered by more than 200mm.

Bottom masonry construction technology

  • 1) The breathable bricks and nozzle seat bricks must be placed flat and in the correct position.
  • 2) After the nozzle seat bricks and breathable bricks are in place, the gaps between them and the surrounding bottom bricks are filled with corundum cement.

Pouring construction requirements

  • 1) Check construction equipment, mixers, water supply, vibrators, etc.
  • 2) Turn on the mixer, add the mixture, dry mix for 1 minute, then add 2/3 of the water. Then slowly add the remaining water and mix wetly for 3 to 5 minutes before discharging.
  • 3) Use a vibrating rod to vibrate after each pouring of the rolling material, and the pouring material is required to be fully exhausted.
  • 4) The pouring construction must be consistent before and after, and the stop time during the process shall not exceed 20 minutes.

Construction requirements for bottom excavation and repair

  • 1) Remove the seat bricks and their surrounding cementing material and clean them.
  • 2) Lift the new breathable bricks and seat bricks into their placement locations.
  • 3) Use corundum cement to fill the gaps between the breathable bricks, the nozzle bricks and the bottom alumina-magnesia carbon bricks.

Good construction technology, coupled with the correct construction by skilled construction workers, can not only ensure the high performance of the refractory lining material but also very likely increase the service life of the refractory lining. To purchase high-quality ladle lining refractory materials, please choose RS Kiln Refractory Factory. We not only provide high-quality refractory lining materials, but we also provide comprehensive customer service to ensure the efficient operation of refractory materials.